That cel you have of Pluto and Venus is from (I
believe) ep 168. It's from the very beginning of
Stars, with the Nehellania returning story arc.
That's the only time Pluto and Minako are ever
paired together alone, as they are stranded in
one of Nehellania's illusions (Pluto gives Venus
a lovely little pep talk on being a leader ^-^).
You might have alreayd known this, but just
thought I hsould let ya know! Ja!